Vol. 6, №1, 2014
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SERGEY PAVLOVICH GUBIN - 75


CLUSTER CHEMISTRY AT NIKOLAEV INSTITUTE OF INORGANIC CHEMISTRY
Samoylov Pavel P., Fedin Vladimir P.
Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, Siberian Branch, http://www.niic.ncs.ru
3, Acad. Lavrentiev ave., 630090 Novosibirsk, Russian Federation
cluster@niic.nsc.ru

The goal of this review article is to summarize history and development of fundamental studies in cluster chemistry at Nikolaev Institute of Inorganic Chemistry, Novosibirsk. The first studies in the Institute related to this area began in the mid-60’s last century. In these studies novel cluster chalcogenides and chalcohalides for the early transition metals were obtained. Extending the range of objects and change the direction of research occurred in the early 80s under supervision of Professor S.P. Gubin, Director of Nikolaev Institute. New methods for extrusion of cluster complexes from polymeric solid state materials were developed. Cluster complexes were modified in solutions and further used for synthesis of novel solid-state materials. New types of clusters of different nuclearty were obtained, structurally characterized, reactivity in solutions were thoroughly investigated. In the last decade our study covers the following directions: a) deliberate synthesis of nanosized clusters (molecular clusters of clusters) from complementary building blocks; b) chemistry of metal(cluster)-cyanide and metal(cluster)-organic micro- and mesoporous framework materials with permanent porosity for gas storage, separation, sensing and catalysis; c) directed synthesis of highly ordered supramolecular assemblies based on large cluster building units and macrocyclic cavitands.

Keywords: coordination compounds, the cluster complexes

UDC 546.85+546.75+546.71

Bibliography – 89 references
Received 09.04.12

RENSIT, 2012, 4(2):14-27
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