Perspectives for X-ray reflectometry with laboratory sources applied to the analysis of thin films at the surface of multicomponent liquids
Viktor E. Asadchikov, Yuri O. Volkov, Alexander D. Nuzhdin, Boris S. Roshchin
Federal Research Center “Crystallography and Photonics” of RAS, http://crys.ras.ru/
Moscow 119333, Russian Federation
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Alexey M. Tikhonov
Kapitza Institute for Physical Problems of RAS, http://kapitza.ras.ru/
Moscow 119334, Russian Federation
Received January 23, 2020; reviewed January 30, 2020; accepted February 04, 2020
The authors present a review of the systematic studies of the structure of macroscopically planar thin films at the air-liquid interface (water, alkali solution and silica hydrosol). A common feature of the considered works is the application of a model-independent approach to the analysis of X-ray reflectometry data, which does not require a priori assumptions about the structure of the object under study. It is shown that the experimental results obtained with the laboratory source in some cases are qualitatively on par with the results of those obtained with the use of synchrotron radiation source. The reproducibility of the effect of spontaneous ordering in films of amphiphilic organic molecules (phospholipids) at the surface of the colloidal solution of silica nanoparticles is demonstrated. The possibility of influencing the kinetics of the in situ formation of a phospholipid film by enriching the liquid substrate with alkali metal ions is also discussed.
: X-ray reflectometry, phospholipids, Langmuir films
, 2020, 12(1):145-152.
Full-text electronic version of this article - web site http://en.rensit.ru/vypuski/article/312/12(1)145-152e.pdf